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PART V
MINERAL FUELS
CHAPTER XXII
COAL AND ITS CLASSIFICATION 1
FueLs are materials which give off sufficient heat when
burnt to be of use in an ordinary fireplace, furnace, or burner.
The burning of a fuel is the combination of one or more
of its constituents with the oxygen of the air, Most bodies
give off heat when combining with oxygen, but they are
only regarded as fuel if they can be used extensively as a
source of heat,
The important mineral fuels are coal, mineral oil, and
peat. Other minerals serve as fuel under special conditions ;
pyrites is used in pyritic smelting, when both its constituents,
iron and sulphur, give off heat; and oil is distilled from
oil-shale. The chief fuels belong to the carbonaceous series,
and depend on carbon or compounds of carbon with hydrogen.
Coal is the fuel of supreme importance in the modern world.
Wood and oil are its only serious rivals. Ordinary wood
(e.g. ash, oak, and elm) has a calorific value of only 35420
British Thermal Units (B.T.U.)% while coal varies from
I For coal in general, cf. E. S. Moore, Coal, 1922.
A B.T.U. is the heat required to raise the temperature of a pound
of water 1° F. (usually taken from 60° to 61° F.). A calorie is the heat
required to raise a gram of water 1° C., usually taken from 14°to 15°C.
To convert B.T.U. to calories multiply by $.” Calorific value is deter.
mined by combustion in a calorimeter ; but it can be estimated from the
analysis by various formule such as that of Dulong. This formula,
adapted to later determinations of the fue] values, is 8100 C + 24,500
(H — 30) Sz2250 x 2, in which C,H, O and S are the weights of the
carbon, hydrogen, oxygen, and S. “Hence of a good bituminous coal with
e.g. sulphur 1 per cent., hydrogen 5 per cent, carbon 74 per cent., and
oxygen 7 per cent., the calorific value would be 1 3,468 B.T.U.
259