164
ECONOMIC GEOLOGY
diamonds are based on the belief that microscopic diamonds
have been made artificially by the reduction of carbon at
high temperatures and under great pressure in the presence
of metallic iron, lithium, or basic silicates, or by the explosion
of cordite in a bomb. These experiments led to the general
conclusion that most diamonds were formed during the cooling
of ultra-basic igneous rock and native iron. The artificial
production of the diamond is however discredited by the
work of Sir Charles Parsons in continuation of the researches
described in his Bakerian Lecture (Phil. Tr. A., vol. 220,
1926, pp. 67-107). He has examined the specimens ex-
hibited to the British Association by Sir William Crookes,
and analysed numerous specimens that he has himself
made by the methods of Moissan and Crookes; he tells me
that the crystals claimed as artificial diamonds are mostly
silicon carbides, and other complex carbides of the impurities
in the iron, viz. calcium, magnesium, chromium, etc., and
that in his opinion no artificial diamond has yet been made.l
He adds that for many years he believed the crystals, some
of which he exhibited at the Royal Society in 1915, were
diamonds, and that they burnt in oxygen at goo® C. ; but
on repeating this test with rigorous care the most character-
istic crystals were found uncorroded; some few had been
whitened but retained their original form.
Many facts, such as the nature of kimberlite, the matrix
of the diamonds in the chief South African mines, and the
presence in diamonds of hydrocarbons and apophyllite which
would be decomposed at a high temperature (eg. J. C.
Branner, Amer. Journ. Sci., (4), xxxiii, 1912, pp. 25-6, and
G. F. Williams, T7. Amer. I.M E., xxxv, 1905, p. 451), indicate
that the diamond was not formed at a high temperature.
Its geological occurrence is in favour of its formation by the
slow crystallization of carbon set free by the dissociation, prob-
ably of a hydrocarbon or carbon tetrachloride at a moderate
temperature, in material rendered viscous by superheated
steam, as at the root of a mud volcano, or where a pheuma-
tolytic solution is acting at an igneous contact or is pro-
ducing pegmatite.
tH. Le Chatelier remarks (Science et Industrie, 1923, P. 194), “ No
one believes any more in the diamond of Moissan ”’