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PYROLUSITE.
Pyrolusite is a dark grey to iron black mineral composed
of manganese dioxide (Mn0 2 ). It is also known as black oxide
of manganese, or, less properly, as black oxide. Owing to the
property it possesses of neutralizing the colour in glass due to
silicate of iron, it is sometimes called glass makers' soap.
USES.
When manganese dioxide and potassium chlorate are mixed
together and heated, oxygen is given off. This is one method
adopted for producing oxygen for industrial purposes, but it
is being superseded by the electrolytic and liquid air methods.
Pyrolusite is used in the manufacturing of electric dry
batteries. It should analyse at least 85 per cent manganese
dioxide and not over one-half of one per cent ferric oxide.
In the melting of bronzes, manganese dioxide is added to
the crucible as a desulphurizer.
As referred to before, pyrolusite is used for counteracting
the green colour of glass due to silicate of iron, introduced by
impurities. Manganese dioxide when added to the glass mix
ture gives a purplish tint, this colour is complementary to the
green and thus destroys it, producing a colourless glass. It
is used for the same purpose in porcelain manufacturing and
enamelling on sheet metal. For these purposes the mineral
should be as free from iron as possible.
Pyrolusite is used extensively in the manufacturing of
varnish. It acts as a drier. For this use it should be high
grade, very finely ground, and free from siliceous impurities.
Prices range, according to purity and quantity purchased,
from $17 to $80. The average price paid by glass manufacturers
is $21 per ton.