RA
ECONOMIC GEOLOGY
which have been intruded by an andesite-porphyry that
grades into quartz-diorite. This intrusion was fractured
and invaded by a superheated boric acid solution which
altered the rock into a mosaic of quartz, tourmaline, sericite,
and rutile, and deposited large quartz-veins containing
sulphides and magnetite. While the andesitic diorite was
still charged with superheated water it was invaded by
dykes of alkaline dacite-porphyry. The consequent rise of
temperature, perhaps combined with release of pressure
owing to fracturing, exploded the superheated water and
blew out a crater 3000 feet in diameter and 6000 feet deep.
This crater was occupied by a lake and gradually filled by
the Braden Tuff being washed into it. Solutions rose along
fractures around the crater, and deposited quartz-veins with
tourmaline and pyrite, and large bodies of ore containing
about I per cent. of copper. The less permeable tuffs re-
ceived lower-grade ores with 4 per cent. of copper. An
alkaline porphyry breccia was upthrust between the tuffs
and the crater wall, and tourmaline was deposited both in
this breccia and the Braden Tuff. As the volcanic activity
waned, the rising solutions were cooler and did not carry
boric acid; they deposited bornite and other sulphides,
sulpharsenites, sulphates, carbonates, and tungstates. Later
still cooler solutions deposited chalcopyrite and bornite,
with quartz and gypsum, which in some of the cavities grew
into crystals 10 feet long. After the volcano had become
wholly extinct, descending meteoric waters leached the ores
from the surface to the depth of 150-300 feet and redeposited
the copper as secondary enrichments of chalcocite. The
Braden Mine therefore illustrates all stages from pneumato-
lytic and contact ores to ordinary quartz-pyrite veins and
secondary enrichments. This association of the different
types is due to volcanic action being local and intense;
in most mining fields the subterranean conditions vary less
quickly.
Lopes or Cornwarr—>Solutions that acted at less depth
and at a lower temperature than those that produced the
pneumatolytic ores and had silicic acid as the predominant
acid, have formed the quartz-copper lodes, which were for
long the chief source of copper. The lodes of Cornwall and
Devon show a transition downward into pneumatolytic tin